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polysilicon

/ˌp ŏ l ē ˈs ĭ l ĭ ˌk ŏ n/

pŏl-y-sĭl-ĭ-cŏn
Rule 1
Vowels usually say their short sound in a closed syllable.
Rule 2
Y says /ē/ only at the end of a multisyllable base word. I says /ē/ at the end of a syllable followed by a vowel and at the end of foreign words.
Rule 3
I and Y may say /ī/ or /ĭ/ at the end of a syllable.
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